Publications
17. The Combination of Synthesis and Ultra-High-Resolution NMR Reveals the Correct Structure of Caylobolide A
George, M.; Deering, M.; Fiorito, D.; Solomon, K.; Tidgewell, K.; Noble, A.; Butts, C.*; Aggarwal, V. K.*
Nat. Synth. 2025, https://doi.org/10.1038/s44160-025-00762-2
16. Bifunctional Photocatalysts Display Proximity-Enhanced Catalytic Activity in Metallaphotoredox C–O Coupling
Dolcini, L.; Solida, A.; Lavelli, D.; Hidalgo-Núñez, A. M.; Gandini, T.; Fornara, M.; Colella, A; Bossi, A.; Penconi, M.; Fiorito, D.; Gennari, C.; Dal Corso, A.; Pignataro, L.*
15. Biocatalytic Approaches for a More Sustainable Synthesis of Sandalwood Fragrances
Cancellieri, M. C.; Maggioni, D.; Di Maio, L.; Fiorito, D., Brenna, E.; Parmeggiani, F.; Gatti, F.*
14. Valorisation of the Industrial Hemp Residue from Essential Oil Production by Recovery of Cannabidiol and Chemo-Enzymatic Conversion to Cannabielsoin
Fiorito, D.; Tessaro, D.; Sangalli, F.; Nobbio, C.; Nebuloni; Vezzini, M.; Brenna, E.; Parmeggiani, F.*
13. Valorization of Lignocellulosic Molecules through Homogeneous Ru‐Catalyzed C−C and C−N Bond Forming Reactions
Fiorito, D.; Ferraccioli, F.*
12. Late-Stage Functionalisation of Pyridine-Containing Bioactive Molecules: Recent Strategies and Perspectives
Failla, M.; Lombardo, G. W.; Orlando, P.; Fiorito, D.; Bombonato, E.; Ronchi, P.; Passarella, D.; Fasano, V.*
Eur. J. Org. Chem. 2023, 26, e202300074
Highlighted in Reader’ Choice in Physical Sciences, Wiley
11. Trapping-Enrichment Multidimensional Liquid Chromatography with On-Line Deuterated Solvent Exchange for Streamlined Structure Elucidation at the Microgram Scale
Haidar Ahmad, I. A. *; Losacco, G. L.; Shchurik, V.; Wang, X.; Cohen, R.; Herron, A. N.; Aiken, S.; Fiorito, D.; Wang, H.; Reibarkh, M.; Nowak, T.; Makarov, A. A.; Stoll, D. R.; Guillarme, D.; Mangion, I.; Aggarwal, V. K.; Yu, J.-Q.; Regalado, E. L.*
10. Stereocontrolled Total Synthesis of Bastimolide B using Iterative Homologation of Boronic Esters
Fiorito, D.; Keskin, S.; Bateman, J. M.; George, M.; Noble, A.; Aggarwal, V. K.*
J. Am. Chem. Soc. 2022, 144, 18, 7995 – 8001
Highlighted in Chemistry World and Chemistry by Design
9. Access to Highly Stereodefined 1,4-cis-Polydienes by a Ni/Mg Orthogonal Tandem Catalytic Polymerization
Fiorito, D.; Simon, M.; Thomas, C. M. *; Mazet, C.*
J. Am. Chem. Soc. 2021, 143, 13401 – 13407
Highlighted in Recent JACS Spotlights
8. Transition Metal-Catalyzed Alkene Isomerization as an Enabling Technology in Tandem, Sequential and Domino Processes
Fiorito, D.‡; Scaringi, S.‡; Mazet, C.* (‡ shared authorship)
7. Direct Access to Chiral Secondary Amides by Copper-Catalyzed Borylative Amidation of Vinylarenes with Isocyanates
Fiorito, D.; Liu, Y.; Besnard, C.; Mazet, C.*
6. Remote Functionalization of α, β-Unsaturated Carbonyls by Multimetallic Sequential Catalysis
Romano, C.; Fiorito, D.; Mazet, C.*
J. Am. Chem. Soc. 2019, 141, 16983 – 16990
Highlighted in Synfacts
5. Ir-Catalyzed Selective Hydroboration of 2-Substituted 1,3-Dienes: A General Method to Access Homoallylic Boronates
Fiorito, D.; Mazet, C.*
4. Copper-Catalyzed Enantioselective 1,2-Borylation of 1,3-Dienes
Liu, Y.; Fiorito, D.; Mazet, C.*
Chem. Sci. 2018, 9, 5284 – 5288 Highlighted in Synfacts
3. A General Nickel-Catalyzed Kumada Vinylation for the Preparation of 2-Substituted 1,3-Dienes
Fiorito, D.; Folliet, S.; Liu, Y.; Mazet, C.*
2. Exploring Site Selectivity of Iridium Hydride Insertion into Allylic Alcohols: Serendipitous Discovery and Comparative Study of Organic and Organometallic Catalysts for the Vinylogous Peterson Elimination
Li, H.‡; Fiorito, D.‡; Mazet, C.* (‡ shared authorship)
1. Synthesis of a 4‐Vinyltetrahydrocarbazole by Palladium‐Catalyzed Asymmetric Allylic Alkylation of Indole‐Containing Allylic Carbonates
Pignataro, L.: Fiorito, D.; Vece, V.; Ferraccioli, R.; Gennari, C.*
Patents
1. Synthetic Methods for the cis-Diol of Cedrene
Italian Patent Application n. 102024000010510 (9/05/2024), Inventors: D. Fiorito, M. E. Brenna.